Accommodating Unwelcome Guests in Inorganic Layered Hosts: Inclusion of Chloranil in a Layered Double Hydroxide

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Accommodating unwelcome guests in inorganic layered hosts: inclusion of chloranil in a layered double hydroxide.

The host-guest chemistry of most inorganic layered solids is limited to ion-exchange reactions. The guest species are either cations or anions to compensate for the charge deficit, either positive or negative, of the inorganic layers. Here, we outline a strategy to include neutral molecules like ortho- and para-chloranil, that are known to be good acceptors in donor-acceptor or charge-transfer ...

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ژورنال

عنوان ژورنال: Inorganic Chemistry

سال: 2012

ISSN: 0020-1669,1520-510X

DOI: 10.1021/ic3002948